Manganese-catalyzed cross-coupling reactions of nitrogen nucleophiles with aryl halides in water

被引：32

作者：

Teo, Yong-Chua ^{[1
]}

Yong, Fui-Fong ^{[1
]}

Poh, Chai-Yun ^{[2
]}

Yan, Yaw-Kai ^{[1
]}

Chua, Guan-Leong ^{[2
]}

机构：

[1] Nanyang Technol Univ, Natl Inst Educ, Singapore 637616, Singapore

[2] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 41期

关键词：

N BOND FORMATION; GRIGNARD-REAGENTS; FORMING REACTIONS; ALIPHATIC-AMINES; EFFICIENT; ARYLATION; CARBON; ORGANOSTANNANES; COMPLEXES; IODIDES;

D O I：

10.1039/b909803h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A facile and convenient strategy for the assembly of N-arylated heterocycles has been demonstrated using a MnCl2 center dot 4H(2)O/trans-1,2-diaminocyclohexane catalyst and K3PO4 as the base in water.

引用

页码：6258 / 6260

页数：3

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