4-[1-(phenylsulfonyl)indol-3-yl]-3a,4,5,9b-tetrahydro-3H-cyclopenta[c]quinoline

被引:0
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作者
Sankaranarayanan, R
Velmurugan, D
Raj, SSS
Fun, HK
Babu, G
Perumal, PT
机构
[1] Univ Madras, Dept Crystallog & Biophys, Chennai 600025, India
[2] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, Penang 11800, Malaysia
[3] Cent Leather Res Inst, Div Organ Chem, Adyar 600020, Chennai, India
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the title compound, C26H22N2O2S, the tetrahydropyridine ring has a conformation intermediate between half-chair and sofa. The tetrahydroquinoline mean plane makes a dihedral angle of 73.3 (1)degrees with the cyclopentene ring, which adopts an envelope conformation, and an angle of 45.45 (4)degrees with the indole best plane, The dihedral angle between the benzene and pyrrole rings is 2.6 (1)degrees. The orientations of the phenyl ring on the sulfonyl group and of the indole are governed by weak C-H ... O interactions. The packing of the molecule in the solid state is stabilized by C-H ... O and C-H ... N hydrogen bonds.
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页码:475 / 476
页数:2
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