Influence of zeolite type on activity of Fischer-Tropsch iron catalysts

被引：7

作者：

Vytnova, L. A. ^{[1
]}

Bogolepova, E. I. ^{[1
]}

Shuikin, A. N. ^{[1
]}

Kurkin, V. I. ^{[1
]}

Marchevskaya, E. V. ^{[1
]}

Kliger, G. A. ^{[1
]}

机构：

[1] Russian Acad Sci, Topchiev Inst Perochem Synth, Moscow 119991, Russia

来源：

PETROLEUM CHEMISTRY | 2006年 / 46卷 / 05期

关键词：

Zeolite; Acid Site; Petroleum Chemistry; Strong Acid Site; Tropsch Synthesis;

D O I：

10.1134/S0965544106050045

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The influence of zeolite type on the product composition, activity, and stability of a binary Fischer-Tropsch iron-containing catalyst was studied. It was shown that the redistribution of acid sites takes place during zeolite shaping with alumina, and, as a result, the relative amount of strong acid sites decreases and the proportion of medium-strength acid sites increases. Zeolites ZSM-5 and ZSM-12 appeared to be the most active in secondary reactions of hydrocarbon conversion under the conditions of hydrocarbon synthesis from CO and H-2.

引用

页码：324 / 331

页数：8

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