Interaction of fullerene C60 with allylbenzene and allyl chloride

被引：0
|
作者：
Yumagulova, R. Kh.
Kolesov, S. V.
Budtov, V. P.
机构：
[1] Russian Acad Sci, Ufa Sci Ctr, Inst Organ Chem, Ufa 450054, Russia
[2] Russian Acad Sci, Inst Macromol Cpds, St Petersburg 199004, Russia
来源：
POLYMER SCIENCE SERIES B | 2006年 / 48卷 / 11-12期
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D O I：
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中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The reaction between allyl compounds and fullerene C-60 has been investigated via dilatometry under the conditions of free-radical polymerization. It has been shown that the rate of a variation in the volume of the reaction mixture plotted versus the concentration of fullerene C-60 is described by a curve with a minimum. It has been established that, in the presence of fullerene and the allyl monomer, the polymerization of methyl methacrylate proceeds without any induction period. It has been concluded that allyl radicals interact with fullerene C-60.
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页码：324 / 327
页数：4
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