Kinetics and mechanism of oxidation of 4-oxoacids by hexacyanoferrate(III) catalysed by Os(VIII)

被引：0

作者：

Rani, DFG

Pushparaj, FJM

Alphonse, I

Rangappa, KS ^{[1
]}

机构：

[1] Univ Mysore, Dept Studies Chem, Mysore 570006, Karnataka, India

[2] Govt Arts Coll, Dept Chem, Ariyalur 621713, India

[3] Govt Arts Coll, Dept Chem, Ooty, India

[4] St Josephs Coll, Dept Chem, Tiruchirappalli 620002, India

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY | 2002年 / 41卷 / 10期

关键词：

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Kinetics of Os(VIII) catalysed oxidation of substituted and unsubstituted 4-oxoacids by alkaline hexacyanoferrate(III) in sodium carbonate-bicarbonate buffer have been studied. The reaction is zero order in oxidant, first order with respect to Os(VIII), first order at higher concentrations and zero order at lower concentrations with respect to both substrate and alkali. The activation parameters have been computed.

引用

页码：2153 / 2159

页数：7

共 50 条

[41] KINETICS AND MECHANISM OF OXIDATION OF ETHANE DIOL BY OS(VIII)
ANAND, BH
MENGHANI, GD
JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1981, 58 (04) : 374 - 376
[42] MECHANISM OF THE OSMIUM(VIII)-CATALYSED OXIDATION OF FURSEMIDE BY ALKALINE HEXACYANOFERRATE(III) AND ANALYSIS OF FURSEMIDE BY A KINETIC AND CATALYTIC METHOD
Billalli, H. B.
Sharanabasamma, K.
Tuwar, S. M.
PROGRESS IN REACTION KINETICS AND MECHANISM, 2010, 35 (04) : 347 - 367
[43] Osmium(VIII) catalysed oxidation of antimony(III) by alkaline hexacyanoferrate(III) and analysis of osmium(VIII) in microamount by a kinetic method
Timmanagoudar, PL
Hiremath, GA
Nandibewoor, ST
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1996, 35 (12): : 1084 - 1090
[44] KINETICS AND MECHANISM OF OXIDATION OF QUINOL BY ALKALINE HEXACYANOFERRATE(III)
BHATTACHARJEE, M
MAHANTI, MK
REACTION KINETICS AND CATALYSIS LETTERS, 1982, 21 (04): : 449 - 454
[45] KINETICS AND MECHANISM OF THE OXIDATION OF HALOTOLUENES BY ACIDIC HEXACYANOFERRATE(III)
BHATTACHARJEE, AK
MAHANTI, MK
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1982, 14 (10) : 1113 - 1124
[46] KINETICS AND MECHANISM OF OSMIUM(VIII)-CATALYZED OXIDATION OF DEUTERIUM-PROLINE AND L(-)-METHIONINE BY HEXACYANOFERRATE(III)
UPADHYAY, SK
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1983, 15 (07) : 669 - 676
[47] Kinetics and mechanism of osmium(VIII)-catalyzed oxidation of 1,4-thioxane by alkaline hexacyanoferrate(III)
Mohammed M. Al-Subu
Transition Metal Chemistry, 2001, 26 : 461 - 464
[48] KINETICS AND MECHANISM OF OSMIUM(VIII)-CATALYZED OXIDATION OF PHOSPHITE BY HEXACYANOFERRATE(III) ION IN AQUEOUS ALKALINE MEDIA
MOHAN, D
GUPTA, YK
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (11): : 1085 - 1089
[49] KINETICS AND MECHANISM OF OSMIUM(VIII) CATALYZED OXIDATION OF BENZYL ALCOHOL AND BENZYLAMINE BY ALKALINE HEXACYANOFERRATE(III) ION
NATH, N
SINGH, LP
REVUE ROUMAINE DE CHIMIE, 1986, 31 (05) : 489 - 496
[50] Kinetics and mechanism of osmium(VIII)-catalyzed oxidation of 1,4-thioxane by alkaline hexacyanoferrate(III)
Al-Subu, MM
TRANSITION METAL CHEMISTRY, 2001, 26 (4-5) : 461 - 464

← 1 2 3 4 5 →