Selective reactions over solid base catalysts

被引：220
|
作者：
Ono, Y
Baba, T
机构：
[1] Department of Chemical Engineering, Tokyo Institute of Technology, Tokyo 152, Ookayama, Meguro-ku
来源：
CATALYSIS TODAY | 1997年 / 38卷 / 03期
关键词：
base catalyst; solid base; organic synthesis;
D O I：
10.1016/S0920-5861(97)81502-5
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A variety of organic reactions are catalyzed in a very selective manner by base catalysts. Especially, solid bases offer convenient and environmentally-benin routes for organic synthesis. This review overviews the recent development on the catalysis by solid bases. The catalytic materials described are zeolites, modified zeolites, alkaline earth oxides, alkali metals on supports, KNH2 on alumina, KF on alumina, hydrotalcites and oxynitrides. Stress are also placed on novel reactions catalyzed by the solid bases. The reactions include isomerization of alkenes, reactions of alkynes, methylations, addition reactions, Knoevenagel condensations, reactions of silanes.
引用
收藏
页码：321 / 337
页数：17
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