A novel nano-palladium catalyst for continuous-flow chemoselective hydrogenation reactions

被引：16
|
作者：
Goszewska, Ilona [1 ]
Gizinski, Damian [1 ]
Zienkiewicz-Machnik, Malgorzata [1 ]
Lisovytskiy, Dmytro [1 ]
Nikiforov, Kostyantyn [1 ]
Masternak, Joanna [2 ]
Srebowata, Anna [1 ]
Sa, Jacinto [1 ,3 ]
机构：
[1] Polish Acad Sci, Inst Phys Chem, Kasprzaka 44-52, PL-01224 Warsaw, Poland
[2] Jan Kochanowski Univ Kielce, Inst Chem, Swietokrzyska 15G, PL-25406 Kielce, Poland
[3] Uppsala Univ, Dept Chem, Angstrom Lab, S-75120 Uppsala, Sweden
来源：
CATALYSIS COMMUNICATIONS | 2017年 / 94卷
关键词：
Flow chemoselective hydrogenation; Nano-Pd grafted on resin; 6-Methyl-5-hepten-2-one; 2-Heptene; SELECTIVE HYDROGENATION; LIQUID; CINNAMALDEHYDE; BINDING; XPS; PD;
D O I：
10.1016/j.catcom.2017.02.014
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Herein, we report a catalyst composed of palladium nanoparticles immobilized on polymeric resin for chemoselective hydrogenation reactions under flow conditions. The catalyst exhibits high activity and selectivity towards hydrogenation of C=C double bond, as confirmed in the hydrogenation of 2-heptene and 6-methyl-5hepten-2-one. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码：65 / 68
页数：4
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