Transfer hydrogenation of aldehydes and ketones with tetrahydroxydiboran in water by an amphiphilic resin-supported nano-palladium catalyst

被引：0
|
作者：
Zhang, Kaili [1 ,2 ]
Okumura, Shintaro [1 ,2 ,3 ]
Uozumi, Yasuhiro [1 ,2 ]
机构：
[1] Inst Mol Sci, Dept Life & Coordinat Complex Mol Sci, Higashiyama 5-1, Okazaki 4440864, Japan
[2] Grad Univ Adv Studies, Mol Sci Program, SOKENDAI, Higashiyama 5-1, Okazaki 4440864, Japan
[3] Kyoto Univ, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan
来源：
CHEMISTRY LETTERS | 2024年 / 53卷 / 05期
基金：
日本学术振兴会;
关键词：
carbonyl compounds; tetrahydroxydiboron; transfer hydrogenation; PLATINUM NANOPARTICLES; NANOPALLADIUM; REDUCTION; DISPERSION; OXIDATION; ALCOHOLS;
D O I：
10.1093/chemle/upae082
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We have developed a transfer hydrogenation of aldehydes and ketones with B-2(OH)(4) as a reductant and amphiphilic resin-dispersed palladium nanoparticles as a catalyst system in an aqueous medium, where water also serves as a hydrogen donor. A variety of aldehydes and ketones, including aliphatic carbonyl compounds, reacted to give the corresponding primary and secondary alcohols, respectively. The catalyst was recovered by filtration and reused 9 times without a significant loss of its catalytic activity.
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页数：4
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