Transfer hydrogenation of aldehydes and ketones with tetrahydroxydiboran in water by an amphiphilic resin-supported nano-palladium catalyst

被引：0

作者：

Zhang, Kaili ^{[1
,2
]}

Okumura, Shintaro ^{[1
,2
,3
]}

Uozumi, Yasuhiro ^{[1
,2
]}

机构：

[1] Inst Mol Sci, Dept Life & Coordinat Complex Mol Sci, Higashiyama 5-1, Okazaki 4440864, Japan

[2] Grad Univ Adv Studies, Mol Sci Program, SOKENDAI, Higashiyama 5-1, Okazaki 4440864, Japan

[3] Kyoto Univ, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan

来源：

CHEMISTRY LETTERS | 2024年 / 53卷 / 05期

基金：

日本学术振兴会;

关键词：

carbonyl compounds; tetrahydroxydiboron; transfer hydrogenation; PLATINUM NANOPARTICLES; NANOPALLADIUM; REDUCTION; DISPERSION; OXIDATION; ALCOHOLS;

D O I：

10.1093/chemle/upae082

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We have developed a transfer hydrogenation of aldehydes and ketones with B-2(OH)(4) as a reductant and amphiphilic resin-dispersed palladium nanoparticles as a catalyst system in an aqueous medium, where water also serves as a hydrogen donor. A variety of aldehydes and ketones, including aliphatic carbonyl compounds, reacted to give the corresponding primary and secondary alcohols, respectively. The catalyst was recovered by filtration and reused 9 times without a significant loss of its catalytic activity.

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页数：4

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