Synthesis of Unsymmetrical Diaryl Selenides: Copper-Catalyzed Se-Arylation of Diaryl Diselenides with Triarylbismuthanes

被引：15

作者：

Matsumura, Mio ^{[1
]}

Shibata, Kohki ^{[1
]}

Ozeki, Sota ^{[1
]}

Yamada, Mizuki ^{[1
]}

Murata, Yuki ^{[1
]}

Kakusawa, Naoki ^{[2
]}

Yasuike, Shuji ^{[1
]}

机构：

[1] Aichi Gakuin Univ, Sch Pharmaceut Sci, Chikusa Ku, 1-100 Kusumoto Cho, Nagoya, Aichi 4648650, Japan

[2] Hokuriku Univ, Fac Pharmaceut Sci, Ho 3 Kanagawa Machi, Kanazawa, Ishikawa 9201181, Japan

来源：

SYNTHESIS-STUTTGART | 2016年 / 48卷 / 05期

关键词：

bismuthanes; diselenides; selenides; copper; catalysis; cross-coupling; BOND FORMATION; N-ARYLATION; DIPHENYL DISELENIDE; ARYLBORONIC ACIDS; ARYL HALIDES; C-SE; CONVENIENT SYNTHESIS; COUPLING REACTIONS; TE BOND; ORGANOSELENIUM;

D O I：

10.1055/s-0035-1561280

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Copper-catalyzed C(aryl)-Se bond formation by the reaction of diaryl diselenides with triarylbismuthanes in the presence of copper(I) acetate (10 mol%) and 1,10-phenanthroline (10 mol%) under aerobic conditions led to the formation of unsymmetric diaryl selenides in moderate to excellent yields. This reaction proceeded efficiently; all three aryl groups in the bismuthane and both the selanyl groups in the diaryl diselenide were transferred to the coupling products.

引用

页码：730 / 736

页数：7

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