Preparation and cationic photopolymerization of organic-inorganic hybrid matrixes

被引：42
|
作者：
Crivello, JV
Mao, ZB
机构：
[1] Department of Chemistry, Rensselaer Polytechnic Institute, Troy
来源：
CHEMISTRY OF MATERIALS | 1997年 / 9卷 / 07期
关键词：
D O I：
10.1021/cm960595q
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Surface modifications of colloidal silica by sol-gel techniques with trialkoxysilane coupling agents bearing cationically polymerizable epoxy and 1-propenyl ether groups were carried out under mild conditions. After dilution with difunctional epoxy and 1-propenyl ether monomers and the addition of an onium salt photoinitiator, the mixtures were irradiated with UV light to provide organic-inorganic hybrid matrixes. Photopolymerizations were uniformly rapid and proceeded to high conversions. Colorless, transparent, cross-linked films potentially useful as abrasion resistant coatings for plastic articles were produced.
引用
收藏
页码：1562 / 1569
页数：8
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