Syntheses and structures of (R2Bi)2E (E = S, Te) and cyclo-(RSbSe)2[W(CO)5]2 [R = CH(SiMe3)2]

被引：28

作者：

Breunig, HJ ^{[1
]}

Ghesner, I ^{[1
]}

Lork, E ^{[1
]}

机构：

[1] Univ Bremen, Inst Anorgan & Phys Chem, D-28334 Bremen, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 664卷 / 1-2期

关键词：

bismuth; antimony selenium; tellurium; tungsten complex; X-ray structure;

D O I：

10.1016/S0022-328X(02)01973-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(R2Bi)(2)E [E = S (1), Te (2); R = CH(SiMe3)(2)] are formed by reaction of R2BiCl with Na2S or Na2Te. The reaction of cyclo (RSbSe)(n) [n = 2, 3; R = CH(SiMe3)(2)] with W(CO)(5)THF (THF = tetrahydrofuran) in THF results in trapping of the dimer in cyclo (RSbSe)(2)[W(CO)(5)](2) (3). The crystal structures of 1, 2, and 3 are reported. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：130 / 135

页数：6

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