CuO-catalyzed oxidation of aryl acetates with aqueous tert-butyl hydroperoxide for the synthesis of α-ketoesters

被引：2
|
作者：
Jiang, Jin [1 ]
机构：
[1] Sichuan Univ Sci & Engn, Sch Chem & Environm Engn, Zigong 643000, Peoples R China
来源：
JOURNAL OF CHEMICAL RESEARCH | 2019年 / 43卷 / 7-8期
关键词：
aryl acetates; CuO; alpha-ketoesters; oxidation; tert-butyl hydroperoxide; KETO ESTERS; ALKYLBENZENES; KETOAMIDES;
D O I：
10.1177/1747519819861317
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A practical method to access alpha-ketoesters from readily available aryl acetates is developed. In this approach, aqueous tert-butyl hydroperoxide and CuO are employed. No additional solvents are required and it was found that the peroxide side products in the reaction can be decomposed by pyridine.
引用
收藏
页码：235 / 240
页数：6
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