Tetra-μ-benzoato-bis{[4-(pyrrolidin-1-yl)pyridine]zinc(II)}

被引：7

作者：

Yu, Seung Man ^{[1
,2
]}

Koo, Kyosang ^{[3
]}

Kim, Pan-Gi ^{[4
]}

Kim, Cheal ^{[1
,2
]}

Kim, Youngmee ^{[5
]}

机构：

[1] Seoul Natl Univ Technol, Dept Fine Chem, Seoul 139743, South Korea

[2] Seoul Natl Univ Technol, Ecoprod & Mat Educ Ctr, Seoul 139743, South Korea

[3] Korea Forest Res Inst, Korea Div Forest Disaster Management, Seoul 130712, South Korea

[4] Kyungpook Natl Univ, Dept Forest & Environm Resources, Sangju 742711, South Korea

[5] Ewha Womans Univ, Dept Chem & Nano Sci, Seoul 120750, South Korea

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

DINUCLEAR; COMPLEXES;

D O I：

10.1107/S1600536809052714

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The central part of the title centrosymmetric dinuclear complex, [Zn(2)(C(7)H(5)O(2))(4)(C(9)H(12)N(2))(2)], has a paddle-wheel conformation with four benzoate ligands bridging two symmetry-related Zn(II) ions. The distorted square-pyramidal coordination environment around the Zn(II) ion is completed by an N atom from a 4-(pyrrolidin-1-yl) pyridine ligand. The Zn center dot center dot center dot Zn separation of 2.9826 (12) angstrom does not represent a formal direct metal-metal bond. The Zn(II) ion is displaced by 0.381(1)angstrom from the mean plane of the four basal O atoms. Two of the C atoms of the pyrrolidine ring are disordered over two sites with refined occupancies of 0.53 (2) and 0.47 (2).

引用

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页码：M61 / U676

页数：12

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