Palladium nanoparticles as reusable catalyst for the synthesis of N-aryl sulfonamides under mild reaction conditions

被引：18

作者：

Khalaj, Mehdi ^{[1
]}

Ghazanfarpour-Darjani, Majid ^{[1
]}

Olyai, Mohamad Reza Talei Bavil ^{[2
]}

Shamami, Sakineh Faraji ^{[3
]}

机构：

[1] Islamic Azad Univ, Buinzahra Branch, Dept Chem, Buinzahra, Iran

[2] Islamic Azad Univ, Fac Sci South Tehran Branch, Dept Chem, Tehran, Iran

[3] Islamic Azad Univ, Karaj Branch, Dept Chem, Karaj, Iran

来源：

JOURNAL OF SULFUR CHEMISTRY | 2016年 / 37卷 / 02期

关键词：

Sulfonamide; aryl halide; C-N Cross-coupling; palladium nanoparticles; aryl triflate; SUZUKI COUPLING REACTION; LIGAND-FREE; BORONIC ACIDS; COPPER; ARYLATION; BROMIDES; IODIDES; DERIVATIVES; CHLORIDES; SULFONYL;

D O I：

10.1080/17415993.2015.1122010

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient palladium nanoparticles-catalyzed N-arylation of sulfonamides and sulfonyl azides is described. This procedure serves as an active protocol for intermolecular C-N bond formation using Pd(OAc)(2) in PEG-400 under air. Aryl bromides and triflates react at 35 degrees C, while aryl chlorides require heating to 50 degrees C and give the desired products only in low yields. This reaction proceeds smoothly in acceptable yields using low catalyst loading.

引用

页码：211 / 221

页数：11

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