Derivatives of (S)-{[2-(methoxymethyl)pyrrolidin-1-yl]-methyl}ferrocene -: New planar chiral ligands

被引：3
|
作者：
Sebesta, R [1 ]
Salisová, M [1 ]
机构：
[1] Comenius Univ, Fac Nat Sci, Dept Organ Chem, Bratislava 84215, Slovakia
来源：
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS | 2002年 / 67卷 / 11期
关键词：
amino alcohols; ferrocenes; metallocenes; ferrocenyl ligands; planar chirality; asymmetric catalysis; diethylzinc addition;
D O I：
10.1135/cccc20021700
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
New planar chiral amino-alcohol ferrocene ligands based on (S)-2-(methoxymethyl) pyrrolidine were synthesized and employed in the enantioselective addition of diethylzinc to benzaldehyde with enantioselectivity up to 82%. The effect of planar chirality was evaluated.
引用
收藏
页码：1700 / 1708
页数：9
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