Solar fuels and feedstocks: the quest for renewable black gold

被引:25
|
作者
Sayre, Hannah J. [1 ]
Tian, Lei [1 ]
Son, Minjung [2 ,3 ]
Hart, Stephanie M. [3 ]
Liu, Xiao [4 ]
Arias-Rotondo, Daniela M. [5 ]
Rand, Barry P. [4 ]
Schlau-Cohen, Gabriela S. [3 ]
Scholes, Gregory D. [1 ]
机构
[1] Princeton Univ, Dept Chem, Princeton, NJ 08544 USA
[2] Univ Wisconsin, Dept Chem, 1101 Univ Ave, Madison, WI 53706 USA
[3] MIT, Dept Chem, Cambridge, MA 02139 USA
[4] Princeton Univ, Dept Elect Engn, Princeton, NJ 08544 USA
[5] Kalamazoo Coll, Dept Chem, Kalamazoo, MI 49007 USA
关键词
C-H BONDS; VISIBLE-LIGHT IRRADIATION; PHOTOINDUCED CHARGE SEPARATION; HIGHLY-SELECTIVE OXIDATION; PHOTOREDOX CATALYSIS; HETEROGENEOUS PHOTOCATALYSIS; HYDROGEN-PRODUCTION; ELECTRON-TRANSFER; TRANSITION-METAL; AROMATIC-ALDEHYDES;
D O I
10.1039/d0ee03300f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Photocatalysis for organic synthesis is a tool capable of C-C, C-O and C-N bond transformations. This technology has the potential to transform the chemical manufacturing industry and support growing demand for chemical feedstocks. Compared to traditional catalysis, photocatalysis can access alternative reaction pathways that lower the overall energy requirement and operate at or near ambient conditions. A key challenge is the delivery of photoenergy at the scale required for rapid and efficient operation of the catalyst. The development of efficient, broad-spectrum light harvesting devices that funnel light energy to a catalyst, along with catalyst design to selectively enable high-energy reactions, are necessary steps towards solar fuels and feedstocks. This perspective highlights some recent advances in photocatalysis and advocates for expanding the scope of photocatalysis for large-scale industrial applications.
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页码:1402 / 1419
页数:18
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