Rhodium(iii)-catalyzed annulation of enamides with sulfoxonium ylides toward isoquinolines

被引：11

作者：

Hong, Chao ^{[1
]}

Yu, Shuling ^{[1
]}

Liu, Zhanxiang ^{[1
]}

Zhang, Yuhong ^{[1
,2
]}

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China

[2] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China

来源：

RSC ADVANCES | 2021年 / 11卷 / 19期

关键词：

C-H FUNCTIONALIZATION; CATALYZED CYCLIZATION; N-OXIDES; DERIVATIVES; ACTIVATION; ALKYNES; ARYL; BONDS; OXIDANT; ESTERS;

D O I：

10.1039/d1ra01063h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient rhodium(iii)-catalyzed C-H activation followed by intermolecular annulation between enamides and sulfoxonium ylides has been developed. The transformation proceeds smoothly with a broad range of substrates, affording a series of isoquinoline derivatives in moderate to good yields under additive-free conditions.

引用

页码：11490 / 11494

页数：5

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