Synthesis and Luminescence Properties of YF3:Ce3+/Tb3+ Nanocrystals

被引:2
|
作者
Wang, Guofeng [1 ,3 ]
Qin, Weiping [1 ]
Zhang, Daisheng [1 ,2 ]
Wei, Guodong [1 ]
Zheng, Kezhi [1 ]
Wang, Lili [1 ]
Ding, Fuheng [1 ]
机构
[1] Jilin Univ, Coll Elect Sci & Engn, State Key Lab Integrated Optoelect, Changchun 130012, Peoples R China
[2] Beihua Univ, Coll Phys, Jilin 132011, Peoples R China
[3] Tsinghua Univ, Dept Chemstry, Beijing 100084, Peoples R China
关键词
Rare Earth; Nanocrystals; Luminescence; Energy Transfer; UP-CONVERSION; HYDROTHERMAL SYNTHESIS; NANOPARTICLES; UNIFORM; GROWTH; EU;
D O I
10.1166/jnn.2010.2119
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
YF3:Ce3+, YF3:Tb3+, and YF3:Ce3+/Tb3+ nanocrystals were synthesized by an ethylenediaminetetraacetic acid (EDTA)-assisted hydrothermal method and characterized by X-ray diffraction and scanning electron microscope. In the excitation spectra, there is one broad excitation band at 285 nm for YF3:Ce3+ and 255 nm for YF3:Tb3+, which are related to the f-d excitations of the Ce3+ and Tb3+ in the host, respectively. In the emission spectra of YF3:Ce3+/Tb3+ nanocrystals under different excitation wavelengths (285 and 255 nm), both spectra exhibit the emissions of Ce3+ and Tb3+, indicating that energy transfer could take place not only from Ce3+ to Tb3+ but also from Tb3+ to Ce3+ ions.
引用
收藏
页码:1939 / 1942
页数:4
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