Synthesis and characterization of new ortho-acetyl or ortho-bis-P-aminophenoxy phosphonate monomers

被引:4
|
作者
Consiglio, GA [1 ]
Failla, S [1 ]
Finocchiaro, P [1 ]
Siracusa, V [1 ]
机构
[1] Univ Catania, Inst Chim, Fac Ingn, Dept Chem & Met Engn, I-95125 Catania, Italy
关键词
electrophilic condensations; monomers for polycondensates; NMR and FAB characterizations; nucleophilic substitutions;
D O I
10.1080/10426500214564
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Some new aryl phosphonic acid ethyl ester analogs of acetyl salicylic acids, and bis-p-aminophenoxy-benzo-phosphonic acid ethyl esters have been prepared in good yield. Characterization by spectroscopic techniques indicates that in the phosphorus NMR spectra a significant change in chemical shift values between the starting phenolic phosphonate and both the corresponding derivative is observed; thus this up-field shift is very diagnostic for this type of compounds.
引用
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页码:2561 / 2569
页数:9
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