Zirconium-mediated asymmetric Baeyer-Villiger oxidation

被引：0

作者：

Bolm, C ^{[1
]}

Beckman, O ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52074 Aachen, Germany

来源：

CHIRALITY | 2000年 / 12卷 / 5-6期

关键词：

oxygen insertion; asymmetric synthesis; optically active butyrolactones; zirconium; atropisomers;

D O I：

10.1002/(SICI)1520-636X(2000)12:5/6<523::AID-CHIR39>3.3.CO;2-Q

中图分类号：

R914 [药物化学];

学科分类号：

100701 ;

摘要：

Combinations of axially chiral C-2-symmetric diols were used as ligands in zirconium-mediated Baeyer-Villiger reactions. The in situ preformed Zr-diol species proved effective in the asymmetric oxidation of bicyclic and monosubstituted cyclobutanones when a hydroperoxide was employed as oxidant. Asymmetric induction could be preserved upon replacement of one out of two enantiopure BINOL ligands by conformationally flexible 2,2'-biphenol. (C) 2000 Wiley-Liss, Inc.

引用

页码：523 / 525

页数：3

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