NMR study of water molecules confined in extended nanospaces

被引：163
|
作者：
Tsukahara, Takehiko
Hibara, Akihide
Ikeda, Yasuhisa
Kitamori, Takehiko
机构：
[1] Univ Tokyo, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan
[2] Tokyo Inst Technol, Nucl Reactors Res Lab, Meguro Ku, Tokyo 1528550, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 07期
关键词：
confinement effects; molecular dynamics; nanotechnology; NMR spectroscopy;
D O I：
10.1002/anie.200604502
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) Does water suffer from claustrophobia? The local structural and dynamic properties of water in confined (300-4000 nm) spaces were characterized by an NMR study of the size-dependent relaxation phenomena, which in turn reflect changes in water mobility and proton transfer. The results are important for understanding fluidics in extended nanospaces and in implementing micro-/nanofluidic devices. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：1180 / 1183
页数：4
相关论文
共 50 条
  • [21] NMR study of flip motion of the water molecules in SNP
    Tritt-Goc, J.
    Pislewski, N.
    Goc, R.
    Physica Status Solidi (A) Applications and Materials Science, 1987, 100 (01):
  • [22] Melting point depression of ionic liquids confined in nanospaces
    Kanakubo, M
    Hiejima, Y
    Minami, K
    Aizawa, T
    Nanjo, H
    CHEMICAL COMMUNICATIONS, 2006, (17) : 1828 - 1830
  • [23] Supramolecular Strategies for Controlling Reactivity within Confined Nanospaces
    Wang, Kaiya
    Jordan, Jacobs H.
    Hu, Xiao-Yu
    Wang, Leyong
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (33) : 13712 - 13721
  • [24] Quantitative Evaluation of Biological Reaction Kinetics in Confined Nanospaces
    Yu, Jiachao
    Luo, Peicheng
    Xin, Chuanxian
    Cao, Xiaodong
    Zhang, Yuanjian
    Liu, Songqin
    ANALYTICAL CHEMISTRY, 2014, 86 (16) : 8129 - 8135
  • [25] NMR study of microscopic mechanism of water molecules diffusion in natrolite
    Sapiga, A., V
    Sergeev, N. A.
    SOLID STATE NUCLEAR MAGNETIC RESONANCE, 2019, 97 : 1 - 6
  • [26] Vibrational spectroscopic study on the phase transition of water in nanospaces and at interfaces
    Yui, Hiroharu
    Morisaku, Toshinori
    Suzuki, Akira
    SURFACE AND INTERFACE ANALYSIS, 2019, 51 (01) : 136 - 140
  • [27] Differential scanning calorimetry and NMR study of water confined in a mesoporous bioactive glass
    Rjiba, Abdelkarim
    Khoder, Hassan
    Jelassi, Jawhar
    Bouguet-Bonnet, Sabine
    Gardiennet, Carole
    Bendeif, El-Eulmi
    Gansmueller, Axel
    Dorbez-Sridi, Rachida
    MICROPOROUS AND MESOPOROUS MATERIALS, 2021, 316
  • [28] Single-File Diffusion of Confined Water Inside SWNTs: An NMR Study
    Das, Anindya
    Jayanthi, Sundaresan
    Deepak, Handiganadu Srinivasa Murthy Vinay
    Ramanathan, Krishna Venkatachala
    Kumar, Anil
    Dasgupta, Chandan
    Sood, Ajay K.
    ACS NANO, 2010, 4 (03) : 1687 - 1695
  • [29] Neutron scattering study on dynamics of water molecules confined in MCM-41
    Takahara, S
    Kittaka, S
    Mori, T
    Kuroda, Y
    Yamaguchi, T
    Bellissent-Funel, MC
    ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY, 2005, 11 (Suppl 1): : 479 - 483
  • [30] Molecular dynamics study of water molecules confined in carbon nanotubes with different helicity
    Wang, J
    Zhu, Y
    Zhou, J
    Lu, XH
    ACTA CHIMICA SINICA, 2003, 61 (12) : 1891 - 1896
12345