μ-Oxo-bis{{2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenolato}oxorhenium(V)}

被引：0
|
作者：
Huang, WT [1 ]
Lo, JM
Yao, HH
Liao, FL
机构：
[1] Yuanpei Tech Coll, Dept Radiol Technol, Hsinchu, Taiwan
[2] Natl Tsing Hua Univ, Dept Nucl Sci, Hsinchu, Taiwan
[3] Natl Tsing Hua Univ, Dept Chem, Hsinchu, Taiwan
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2000年 / 56卷
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound, [Re2O3(C19H20N2O2)(2)], is a hexacoordinate complex containing an [Re2O3](4+) core with a linear O=Re-O-Re=O bridge. The distorted octahedral coordination of the Re-V atom is achieved by an N2O2 donor set from the tetradentate imine-phenol ligand. The overall charge of the compound is neutral due to deprotonation of the phenol groups, and the terminating and bridging O atoms. The Re O and Re-O bond distances of the [Re2O3](4+) core are 1.699 (4) and 1.911 (1) Angstrom, respectively. The Re-O and Re-N bond distances of the equatorial plane are in the ranges 2.024 (4)-2.013 (4) and 2.128 (5)-2.120 (5) Angstrom, respectively.
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页码：E172 / E173
页数：2
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