Catalytic enantioselective boron conjugate addition to cyclic carbonyl compounds: a new approach to cyclic β-hydroxy carbonyls

被引：100

作者：

Feng, Xinhui

Yun, Jaesook ^{[1
]}

机构：

[1] Sungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 43期

关键词：

ALPHA; BETA-UNSATURATED ESTERS; DIBORON REAGENTS; BETA-EPOXY KETONES; ASYMMETRIC-SYNTHESIS; EFFICIENT SYNTHESIS; BORATION; BIS(PINACOLATO)DIBORON; AMIDES; 1,4-DIBORATION; REDUCTION;

D O I：

10.1039/b914207j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The highly enantioselective conjugate boration of six-membered and seven-membered cyclic enones and unsaturated esters was achieved by the use of a copper-(R,S)-Taniaphos complex with up to 99% cc under optimal conditions.

引用

页码：6577 / 6579

页数：3

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