Catalytic enantioselective boron conjugate addition to cyclic carbonyl compounds: a new approach to cyclic β-hydroxy carbonyls

被引：100
|
作者：
Feng, Xinhui
Yun, Jaesook [1 ]
机构：
[1] Sungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea
来源：
CHEMICAL COMMUNICATIONS | 2009年 / 43期
关键词：
ALPHA; BETA-UNSATURATED ESTERS; DIBORON REAGENTS; BETA-EPOXY KETONES; ASYMMETRIC-SYNTHESIS; EFFICIENT SYNTHESIS; BORATION; BIS(PINACOLATO)DIBORON; AMIDES; 1,4-DIBORATION; REDUCTION;
D O I：
10.1039/b914207j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The highly enantioselective conjugate boration of six-membered and seven-membered cyclic enones and unsaturated esters was achieved by the use of a copper-(R,S)-Taniaphos complex with up to 99% cc under optimal conditions.
引用
收藏
页码：6577 / 6579
页数：3
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