Tunable Aryl Alkyl Ionic Liquids (TAAILs): The Next Generation of Ionic Liquids

被引：149
|
作者：
Ahrens, Sebastian [2 ]
Peritz, Anke [1 ]
Strassner, Thomas [1 ]
机构：
[1] Tech Univ Dresden, D-01062 Dresden, Germany
[2] BASF SE, D-67056 Ludwigshafen, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 42期
关键词：
imidazolium salts; ionic liquids; substituent effects; TAAILs;
D O I：
10.1002/anie.200903399
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The combination of aromatic and aliphatic substituents at the imidazolium ring leads to a new generation of imidazolium-based ionic liquids (TAAILs: tunable aryl alkyl ionic liquids; see charge distribution of the methoxyphenyl methyl derivative). Electronic interaction between the aromatic substituent and the imidazolium core allows the properties ofthese species to be tuned more precisely than is possible for currently available ionic liquids. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
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页码：7908 / 7910
页数：3
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