Magnesium chloride:: an efficient 13C NMR relaxation agent for amino acids and some carboxylic acids

被引：15

作者：

Tian, JP ^{[1
]}

Yin, YW ^{[1
]}

Sun, HB ^{[1
]}

Luo, XF ^{[1
]}

机构：

[1] Tsing Hua Univ, Dept Chem, Beijing 100084, Peoples R China

来源：

JOURNAL OF MAGNETIC RESONANCE | 2002年 / 159卷 / 02期

关键词：

amino acids; carboxylic acids; magnesium chloride; C-13 NMR spectroscopy; C-13 NMR relaxation agent;

D O I：

10.1016/S1090-7807(02)00016-2

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

A series of amino acids and carboxylic acids ere determined by C-13 NMR spectroscopy. The results showed that addition of 3M MgCl2, led to shortening of relaxation time and C-13 NMR integral area of samples was well proportional to the number of carbon atoms with reliability more than 95%. So MgCl2 is proposed as an efficient relaxation agent for analysis of amino acids and some carboxylic acids. (C) 2002 Elsevier Science (USA). All rights reserved.

引用

页码：137 / 144

页数：8

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