Synthesis and X-ray crystal structure of a cyclic hemiorthoester

被引：5
|
作者：
Austin, Kerrie A. B. [1 ]
Banwell, Martin G. [1 ]
Willis, Anthony C. [1 ]
机构：
[1] Australian Natl Univ, Res Sch Chem, Canberra, ACT 0200, Australia
来源：
ARKIVOC | 2006年
关键词：
acetonides; anomeric effect; hemiorthoester; hydrolysis; trifluoromethyl group;
D O I：
10.3998/ark.5550190.0007.d01
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Treatment of the acetonides 1 and 2 with trifluoroacetic acid in the presence of small amounts of water affords, in good yield, the corresponding cyclic hemiorthoesters 5 and 6, respectively. A single crystal X-ray analysis of compound 5 has been carried out.
引用
收藏
页码：1 / 7
页数：7
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