Electrical conduction behavior of La, Co co-doped SrTiO3 perovskite as anode material for solid oxide fuel cells

被引:124
|
作者
Li, Xue [1 ]
Zhao, Hailei [1 ,2 ]
Xu, Nansheng [1 ]
Zhou, Xiong [1 ]
Zhany, Cuijuan [1 ]
Chen, Ning [1 ,2 ]
机构
[1] Univ Sci & Technol Beijing, Dept Inorgan Nonmetall Mat, Beijing 100083, Peoples R China
[2] Beijing Key Lab New Energy Mat & Technol, Beijing 100083, Peoples R China
关键词
Solid oxide fuel cell; Anode; SrTiO3; Electronic and ionic conductivity; Co-doping; CARBON DEPOSITION; SOFC; INTERCONNECT; PERFORMANCE; FE; OXIDATION;
D O I
10.1016/j.ijhydene.2009.05.079
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The effects of La- and Co-doping into SrTiO3 perovskite oxides on their phase structure, electrical conductivity, ionic conductivity and oxygen vacancy concentration have been investigated. The solid solution limits of La in LaxSr1-xTiO3 (-) (delta) and Co in La0.3Sr0.7Coy Ti1-yO3 - delta are about 40 mol% and 7 mol%, respectively, at 1500 degrees C. The incorporation of La decreases the band gap and thus increases the electrical conductivity of SrTiO3 remarkably. La0.3Sr0.7TiO3 - delta shows an electrical conductivity of 247 S/cm at 700 degrees C. Co-doping into La0.3Sr0.7TiO3 - delta increases the oxygen vacancy concentration and decreases the migration energy for oxygen ions, leading to a significant increase in ionic conductivity but at the expense of some electrical conductivity. The electrical and ionic conductivities of La0.3Sr0.7Co0.07Ti0.93O3 - delta are 63 S/cm and 6 x 10(-3) S/cm, respectively, at 700 degrees C. Both La0.3Sr0.7TiO3 - delta and La0.3Sr0.7Co0.07Ti0.93O3 - delta show relatively stable electrical conductivities under oxygen partial pressure of 10(-14)-10(-19) atm at 800 degrees C. These properties make La0.3Sr0.7Co0.07Ti0.93O3 - delta a promising anode candidate for solid oxide fuel cells. (C) 2009 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:6407 / 6414
页数:8
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