Fluorinated and hemifluorinated surfactants derived from maltose: Synthesis and application to handling membrane proteins in aqueous solution

被引：22
|
作者：
Polidori, Ange
Presset, Marc
Lebaupain, Florence
Ameduri, Bruno
Popot, Jean-Luc
Breyton, Cecile
Pucci, Bernard
机构：
[1] Univ Avignon & Pays Vaucluse, Lab Chim Bioorgan & Syst Mol Vectoriels, F-84000 Avignon, France
[2] CNRS, UMR 7099, Lab Physicochim Mol Membranes Biol, F-75005 Paris, France
[3] Univ Paris 07, CNRS, Inst Biol Physicochim, FRC 550, F-75005 Paris, France
[4] ENSCM, Lab Chim Macromol, F-34296 Montpellier 5, France
来源：
BIOORGANIC & MEDICINAL CHEMISTRY LETTERS | 2006年 / 16卷 / 22期
关键词：
fluorinated surfactants; maltoside; membrane proteins; solubilization; aggregates;
D O I：
10.1016/j.bmcl.2006.08.070
中图分类号：
R914 [药物化学];
学科分类号：
100701 ;
摘要：
Two novel fluorinated surfactants have been obtained by grafting by radical reaction either a fluorocarbon or an ethyl end-capped fluorocarbon chain onto the double bond of beta-D-allyl maltose. The two compounds thus obtained form polydisperse aggregates in water. They can keep membrane proteins water-soluble, but the protein/surfactant complexes are polydisperse, which affects neither the native state nor the stability of the proteins. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码：5827 / 5831
页数：5
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