Unique magnetic behavior in a one-dimensional coordination polymer [Co(tmpyim)2(tp)]

被引：0
|
作者：
Li, LC [1 ]
Liu, ZL
Turner, SS
Liao, DZ
Jiang, ZH
Yan, SP
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
[2] UCL Royal Inst Great Britain, Davy Faraday Res Lab, London W1S 4BS, England
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2003年 / 01期
关键词：
magnetic properties; crystal structure; radicals; terephthalate;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A one dimensional cobalt(II)-radical complex [Co(tmpyim)(2)(tp)] [tmpyim = 4,4,5,5-tetramethyl-2-(3'-pyridyl)imidazoline-1-oxyl 3-oxide and tp = terephthalate dianion] has been synthesized and characterized by X-ray crystallography. The crystal structure consists of infinite chains of Co(tmpyim)(2) units cross-linked by terephthalate ligands. The magnetic behavior of the complex is unique and is discussed in connection with the crystal structure. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).
引用
收藏
页码：62 / 65
页数：4
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