Electrochemical impedance study of anode CO-poisoning in PEM fuel cells

被引：0

作者：

Ciureanu, M ^{[1
]}

Wang, H ^{[1
]}

机构：

[1] H Power Enterprises Canada Inc, St Laurent, PQ H4R 1V8, Canada

来源：

JOURNAL OF NEW MATERIALS FOR ELECTROCHEMICAL SYSTEMS | 2000年 / 3卷 / 02期

关键词：

electrochemical impedance; CO-poisoning;

D O I：

暂无

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

In situ Electrochemical Impedance Spectroscopy (EIS) is used as a diagnostic tool to provide information on the processes responsible for the activity loss of anodes in PEM fuel cells in the presence of CO. The impedance spectra on Pt and Pt50Ru50 gas diffusion electrodes are presented and compared at various potentials, in an attempt to furnish new criteria for characterizing the CO tolerance of electrocatalysts. Changes of the EIS pattern as a function of CO concentration, catalyst loading and temperature are also presented and discussed comparatively for Pt and PtRu. Arguments are presented to support the hypothesis that the better CO tolerance of PtRu as compared with Pt is mainly determined by a higher ratio between the rates of oxidative removal of CO and CO re-adsorption. A new criterion, based on EIS, is proposed for defining the CO tolerance of electrocatalysts.

引用

页码：107 / 119

页数：13

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