Selective oxidation of alcohols with H2O2 catalyzed by zinc polyoxometalate immobilized on multi-wall carbon nanotubes modified with ionic liquid

被引:26
|
作者
Hajian, Robabeh [1 ]
Alghour, Zahra [1 ]
机构
[1] Yazd Univ, Dept Chem, Yazd 89195741, Iran
关键词
Immobilized ionic liquid; PZnMo2W9O39](5-); Hydrogen peroxide; Oxidation; Alcohol; Heterogeneous catalyst; FUNCTIONALIZATION;
D O I
10.1016/j.cclet.2016.12.003
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this work, acid functionalized multi-wall carbon nanotubes (MVVCNTs) were modified with imidazolium-based ionic liquids. The selective oxidation of various alcohols with hydrogen peroxide catalyzed by [PZnMo2W9O39](5-), ZnPOM, supported on ionic liquids-modified with MWCNTs, MWCNTAPIB, is reported. This catalyst [ZnPOM@APIB-MWCNT], was characterized by X-ray diffraction, scanning electron microscopy (SEM) and FT-IR spectroscopic methods. This heterogeneous catalyst exhibited high stability and reusability in the oxidation reaction without loss of its catalytic performante. (C) 2016 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:971 / 975
页数:5
相关论文
共 50 条
  • [31] Selective ammoximation of ketones and aldehydes catalyzed by a trivanadium-substituted polyoxometalate with H2O2 and ammonia
    Xue, Xiaoling
    Song, Fangyuan
    Ma, Baochun
    Yu, Yongze
    Li, Cheng
    Ding, Yong
    CATALYSIS COMMUNICATIONS, 2013, 33 : 61 - 65
  • [33] Selective oxidation of alcohols with H2O2 catalyzed by long chain multi-SO3H functionalized heteropolyanion-based ionic liquids under solvent-free conditions
    Li, Xinzhong
    Cao, Rong
    Lin, Qi
    CATALYSIS COMMUNICATIONS, 2015, 69 : 5 - 10
  • [34] H2O2 Detection at Carbon Nanotubes and Nitrogen-Doped Carbon Nanotubes: Oxidation, Reduction, or Disproportionation?
    Goran, Jacob M.
    Phan, Ethan N. H.
    Favela, Carlos A.
    Stevenson, Keith J.
    ANALYTICAL CHEMISTRY, 2015, 87 (12) : 5989 - 5996
  • [35] Selective Oxidation of Alkylarene in H2O Catalyzed by the Polyoxometalate Supported Chromium Catalyst
    Zhao, Chengchun
    Xie, Ya
    Shi, Da
    Yu, Han
    CHEMCATCHEM, 2023, 15 (11)
  • [36] Deep oxidative desulfurization of fuels catalyzed by ionic liquid in the presence of H2O2
    Lu, Liang
    Cheng, Shifu
    Gao, Jinbao
    Gao, Guohua
    He, Ming-yuan
    ENERGY & FUELS, 2007, 21 (01) : 383 - 384
  • [37] Green oxidation of sulfides to sulfoxides and sulfones with H2O2 catalyzed by ionic liquid compounds based on Keplerate polyoxometalates
    Fareghi-Alamdari, Reza
    Zekri, Negar
    Moghadam, Ahmad Jamali
    Farsani, Mostafa Riahi
    CATALYSIS COMMUNICATIONS, 2017, 98 : 71 - 75
  • [38] Biomimetic oxidation of veratryl alcohol with H2O2 catalyzed by iron(III) porphyrins and horseradish peroxidase in ionic liquid
    Kumar, Anil
    Jain, Nidhi
    Chauhan, S. M. S.
    SYNLETT, 2007, (03) : 411 - 414
  • [39] New synthesis of Cu2O and Cu nanoparticles on multi-wall carbon nanotubes
    Martinez-Ruiz, A.
    Alonso-Nunez, G.
    MATERIALS RESEARCH BULLETIN, 2008, 43 (06) : 1492 - 1496
  • [40] Electrochemical behaviour of antioxidants: Part 2. Electrochemical oxidation mechanism of quercetin at glassy carbon electrode modified with multi-wall carbon nanotubes
    Abdel-Hamid, Refat
    Rabia, Mostafa K.
    Newair, Emad F.
    ARABIAN JOURNAL OF CHEMISTRY, 2016, 9 (03) : 350 - 356