Reactions of N- and C-alkenylanilines:: IV.: Synthesis of heterocycles by oxidation of N-acyl-o-(1-alkenyl)anilines with hydrogen peroxide

被引：7

作者：

Gataullin, RR ^{[1
]}

Nasyrov, MF ^{[1
]}

Abdrakhmanov, IB ^{[1
]}

Tolstikov, GA ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Organ Chem, Ufa Res Ctr, Ufa 450054, Bashkortostan, Russia

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 38卷 / 10期

关键词：

Oxidation; Hydrogen; Hydrogen Peroxide; Organic Chemistry; Aniline;

D O I：

10.1023/A:1022572909355

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Heterocyclic compounds of the 4H-3,1-benzoxazine and cyclopenta[b]indole series were synthesized by oxydation of N-acyl derivatives of 2-(1-alkenyl)anilines with hydrogen peroxide. The structure of the oxidation products is determined by the reaction conditions, substituent in the ortho-position of the aromatic ring, protecting group, and alkenyl radical structure.

引用

页码：1525 / 1533

页数：9

共 28 条

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[27] Synthesis, IR spectra, and crystal structure of N-(4-bromophenyl)-1,1,1-trifluoroacetylacetonimine, HN(C6H4Br) center dot C(Me) center dot CH center dot C(CF3) center dot O(HL) and the molecular complex of oxotetrachloro tungstene(IV) with It, WOCl4 center dot HL
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