Structures and spectroscopic properties of Ni(II) and Mn(II) complexes based on 5-(3′, 5′-dicarboxylphenyl) picolinic acid ligand

被引：8
|
作者：
Ma, Qi [1 ]
Song, Jin-Ping [1 ]
Su, Feng [2 ]
Guo, Jun-Mei [1 ]
Guo, Yong [1 ]
Dong, Chuan [2 ]
机构：
[1] Shanxi Datong Univ, Inst Appl Chem, Coll Chem & Environm Engn, Datong 037009, Shanxi, Peoples R China
[2] Shanxi Univ, Inst Environm Sci, Taiyuan 030006, Peoples R China
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2016年 / 1111卷
基金：
中国国家自然科学基金;
关键词：
5-(3; 5 '-dicarboxylphenyl) picolinic acid ligand; Stairs-like 2D layer structure; Spectroscopic properties; Hydrogen bonding; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; ZN(II); SERIES; ASSEMBLIES; CLUSTERS; CO(II);
D O I：
10.1016/j.molstruc.2016.01.081
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Two novel complexes including [Ni(Hdcppa)(H2O)(4)] (1) and {[Mn-3(dcppa)(2)(H2O)(6)]center dot 2H(2)O}(n) (2) have been synthesized and characterized by single crystal X-ray structure analysis and elemental analysis. Results show that 1 is a mononuclear nickel(II) compound with octahedron coordination geometry, while 2 is a stairs-like 2D layer structure consisting of the trinuclear Mn-II units linked through dcppa(3-). Spectroscopic and electrochemical properties of the complexes 1-2 have also been studied in dimethyl sulfoxide solution at room temperature. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码：126 / 131
页数：6
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