Imidazole derivative .24. [Li12O2Cl2(ImN)(8)(THF)(4)]center dot 8THF: A peroxo lithium fragment in a novel cage structure

被引：20

作者：

Kuhn, N

Abram, U

MaichleMossmer, C

Wiethoff, J

机构：

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1997年 / 623卷 / 07期

关键词：

lithium; imidazole derivatives; peroxo complexes; crystal structure;

D O I：

10.1002/zaac.19976230719

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

1,3-dimethyl-2-iminoimidazoline (8, ImNH) reacts with methyl lithium to give [ImNLi](n) (9). In tetrahydrofuran, crystals of C56H96Cl2Li12N24O6 . 8C(4)H(8)O (10) are obtained. The structure of 10 consists of a Li12Cl2N8O2 core in which a peroxo unit is incorporated into a stack of ladder fragments. Over all, four tetrahydrofuran and eight imidazoline ligands are attached at the lithium and nitrogen atoms.

引用

页码：1121 / 1124

页数：4

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