Imidazole derivative .24. [Li12O2Cl2(ImN)(8)(THF)(4)]center dot 8THF: A peroxo lithium fragment in a novel cage structure

被引：20
|
作者：
Kuhn, N
Abram, U
MaichleMossmer, C
Wiethoff, J
机构：
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1997年 / 623卷 / 07期
关键词：
lithium; imidazole derivatives; peroxo complexes; crystal structure;
D O I：
10.1002/zaac.19976230719
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
1,3-dimethyl-2-iminoimidazoline (8, ImNH) reacts with methyl lithium to give [ImNLi](n) (9). In tetrahydrofuran, crystals of C56H96Cl2Li12N24O6 . 8C(4)H(8)O (10) are obtained. The structure of 10 consists of a Li12Cl2N8O2 core in which a peroxo unit is incorporated into a stack of ladder fragments. Over all, four tetrahydrofuran and eight imidazoline ligands are attached at the lithium and nitrogen atoms.
引用
收藏
页码：1121 / 1124
页数：4
相关论文
共 50 条
  • [1] Derivate des Imidazols. XXIV. [Li12O2Cl2(ImN)8(THF)4] u 8 THF: ein Peroxo-Komplex des Lithiums mit neuartiger Kaefigstruktur
    Z Anorg Allg Chem, 7 (1121):
  • [2] Syntheses and crystal structure analyses of [SbI3(SbMe3)(THF)]2 and [Li(THF)4]2[Bi2Cl8(THF)2]
    Breunig, HJ
    Denker, M
    Schulz, RE
    Lork, E
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1998, 624 (01): : 81 - 84
  • [3] Synthesis and Crystal Structure of a Novel Ion-pair Complex of [Li(THF)4Nd(C8H8)2]·2THF
    齐贵中
    林永华
    金松春
    沈琪
    Journal of Rare Earths, 1992, (04) : 263 - 266
  • [4] A novel cage organotellurate(IV) macrocyclic host encapsulating a bromide anion guest:: [Li(THF)4][{(PriTe)12O16Br4{Li(THF)Br}4}Br]•2THF
    Citeau, H
    Kirschbaum, K
    Conrad, O
    Giolando, DM
    CHEMICAL COMMUNICATIONS, 2001, (19) : 2006 - 2007
  • [5] THE SYNTHESIS AND STUDY OF TETRANUCLEAR CLUSTER [Fe4O2(CCl3COO)(8)(THF)(2)(DMF)(H2O)]center dot THF
    Prodiusa, Denis
    Mereacrea, Valeriu
    Shovab, Sergiu
    Gdaniecc, Maria
    Simonovd, Yurii
    Soracee, Lorenzo
    Caneschie, Andrea
    Stanicaf, Nicolae
    Gerug, Ion
    Turta, Constantin
    CHEMISTRY JOURNAL OF MOLDOVA, 2006, 1 (01): : 77 - 83
  • [6] X-ray crystallographic structure of Ga-8(pz)(12)O4Cl4 center dot 2thf: A novel gallium pyrazololate complex with a Ga4O4 core
    Capparelli, MV
    Hodge, P
    Piggott, B
    CHEMICAL COMMUNICATIONS, 1997, (10) : 937 - 938
  • [7] Nucleophilic substitution vs acid-base reactions of [Mn{N(SiMe3)(2)}(2)]center dot 2thf; Syntheses and structures of 2[Li(thf)(4)](+)[Mn(C12H8H)(4)](2-)center dot C6H5Me and [Mn(C12H8N)(2)]center dot 3thf (thf equals tetrahydrofuran, C12H8N equals carbazol-9-yl)
    Beswick, MA
    Harmer, CN
    Raithby, PR
    Steiner, A
    Verhorevoort, KL
    Wright, DS
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (12): : 2029 - 2032
  • [8] STRUCTURAL CHARACTERIZATION OF 2 LARGE BISMUTH-COBALT CARBONYL CLUSTERS - (PPN)(2)[BI4CO9(CO)(8)(MU-CO)(8)]CENTER-DOT-2THF AND (PPN)(2)[BI8CO14(CO)(12)(MU-CO)(8)]CENTER-DOT-1.08THF
    WHITMIRE, KH
    EVELAND, JR
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (11) : 1335 - 1336
  • [9] SYNTHESIS AND CHARACTERIZATION OF CIS-[MO6CL8(CL-4) (P(C2H5)(3))(2)]CENTER-DOT-2THF
    EHRLICH, GM
    DENG, H
    HILL, LI
    STEIGERWALD, ML
    SQUATTRITO, PJ
    DISALVO, FJ
    INORGANIC CHEMISTRY, 1995, 34 (09) : 2480 - 2482
  • [10] SYNTHESIS AND CRYSTAL STRUCTURE OF {C（η5-C5H5）4Nd4（μ4-O） （μ2-Cl）8)]·[Li（dme）2THF]2
    Li Xiang-Gao Liu Jing-Zhi Jin Shong-Chun Lin Yong-Hua Liu Guo-Zhi Changchun Institute of Applied Chemistry
    结构化学, 1991, (01) : 60 - 66
12345