Selective Conversion of Alcohols into Alkyl Iodides Using a Thioiminium Salt

被引：17
|
作者：
Ellwood, Adam R. [1 ]
Porter, Michael J. [1 ]
机构：
[1] UCL, Dept Chem, Christopher Ingold Labs, London WC1H 0AJ, England
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2009年 / 74卷 / 20期
关键词：
CHLOROTRIMETHYLSILANE SODIUM IODIDE; HYDROXYL-GROUPS; REAGENT SYSTEM; EFFICIENT; HALIDES; REPLACEMENT; HALOGENATION; CONVENIENT; INVERSION; SULFIDES;
D O I：
10.1021/jo901415n
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Treatment of a range of primary and secondary alcohols with MeSCH=NMe2+ I- affords the corresponding alkyl iodides in excellent yield with straightforward purification. Selective formation of a primary iodide in the presence of a secondary alcohol can be achieved.
引用
收藏
页码：7982 / 7985
页数：4
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