Selective procedure for the conversion of alcohols into alkyl iodides with SO42-/ZrO2 and NaI at room temperature

被引：17
|
作者：
Satam, Jitendra R. [1 ]
Jayaram, Radha V. [1 ]
机构：
[1] Inst Chem Technol, Dept Chem, Bombay 400019, Maharashtra, India
来源：
CATALYSIS COMMUNICATIONS | 2008年 / 9卷 / 06期
关键词：
benzylic alcohol; iodination; iodides; SO42-/ZrO2; saturated alcohol;
D O I：
10.1016/j.catcom.2007.10.004
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
SO42-/ZrO2 was employed as a catalyst for the conversion of alcohols into the corresponding iodides using NaI in CH3CN at room temperature. Present procedure is found to be selective for the conversion of benzylic alcohols in the presence of saturated alcohols into benzylic iodides. The catalyst was characterized by XRD, FTIR, elemental analysis, BET surface area and TG-DTA techniques. This protocol provides a mild and efficient way for the one pot conversion of structurally diverse alcohols to their corresponding alkyl iodides with high selectivity. [GRAPHICS] R = alkyl, allyl, benzyl (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：1033 / 1039
页数：7
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