Synthesis and catalytic activity of three-coordinate zinc cations

被引：75
|
作者：
Hannant, MD [1 ]
Schormann, M [1 ]
Bochmann, M [1 ]
机构：
[1] Univ E Anglia, Sch Chem Sci, Wolfson Mat & Catalysis Ctr, Norwich NR4 7TJ, Norfolk, England
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 22期
关键词：
D O I：
10.1039/b208165m
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction between DADZnR(2) and either B(C6F5)(3) or ZnR2 and [DADH][B(C6F5)(4)] affords three-coordinate alkyl and amide zinc cations which are active for the ring opening polymerisation of epoxides and epsilon-caprolactone [DAD = (MeC =NC6H3Pr2i-2,6)(2)].
引用
收藏
页码：4071 / 4073
页数：3
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