Insertion of alkynes into Ni-H bonds: Synthesis of novel vinyl nickel(II) and dinuclear vinyl nickel(II) complexes containing a [P,S]-ligand

被引：28
|
作者：
She, Lei
Li, Xiaoyan
Sun, Hongjian
Ding, Jun
Frey, Markus
Klein, Hans-Friedrich
机构：
[1] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China
[2] Tech Univ Darmstadt, Fachbereich Chem, D-64287 Darmstadt, Germany
来源：
ORGANOMETALLICS | 2007年 / 26卷 / 03期
关键词：
D O I：
10.1021/om0606340
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reactions of alkynes with nickel hydride complexes bearing a [P, S]-ligand and supported by trimethylphosphine were investigated. Tetracoordinate vinyl nickel(II) complexes 3, 5, and 6 with square-planar geometry were obtained by reacting phenylacetylene, trimethylsilylacetylene, and 1-hexyne with the hydrido nickel complex 1. Reaction of 1,4-bis(trimethylsilylethynyl)benzene with complex 1 proceeds as a monoinsertion and afforded complex 7, while reaction of 1,4-bis(ethynyl)benzene with 1 leads to the dinuclear vinyl nickel(II) complex 8.
引用
收藏
页码：566 / 570
页数：5
相关论文
共 50 条
  • [31] Polymers Containing Nickel(II) Complexes of Goedken's Macrocycle: Optimized Synthesis and Electrochemical Characterization
    Paquette, Joseph A.
    Sauve, Ethan R.
    Gilroy, Joe B.
    MACROMOLECULAR RAPID COMMUNICATIONS, 2015, 36 (07) : 621 - 626
  • [32] Synthesis and characterization of mixed ligand complexes of cobalt(II) and nickel(II) containing trans-[14]-diene and organic monobasic acids
    Islam, MS
    Pal, SC
    Ahmed, S
    Mofizuddin, M
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1996, 35 (07): : 617 - 619
  • [33] Synthesis, structures, and properties of nickel(II) mixed-ligand complexes containing various β-diketonates and a phosphorus donor bidentate ligand
    Arakawa, Machiko
    Miyamae, Hiroshi
    Fukuda, Yutaka
    1600, Chemical Society of Japan (80):
  • [34] Synthesis, structures, and properties of nickel(II) mixed-ligand complexes containing various β-diketonates and a phosphorus donor bidentate ligand
    Arakawa, Machiko
    Miyamae, Hiroshi
    Fukuda, Yutaka
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2007, 80 (05) : 963 - 965
  • [35] Intra- and intermolecular H•••Cl-Ni bonding patterns in a series of highly preorganized dinuclear nickel(II) complexes
    Nie, Feng-Mei
    Leibeling, Guido
    Demeshko, Serhiy
    Dechert, Sebastian
    Meyer, Franc
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2007, 9 (09) : 1233 - 1239
  • [36] Hydrogen Bonds as Structural Directive towards Unusual Polynuclear Complexes: Synthesis, Structure, and Magnetic Properties of Copper(II) and Nickel(II) Complexes with a 2-Aminoglucose Ligand
    Burkhardt, Anja
    Spielberg, Eike T.
    Simon, Sascha
    Goerls, Helmar
    Buchholz, Axel
    Plass, Winfried
    CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (05) : 1261 - 1271
  • [37] Hydrogen bonds as structural directive towards unusual polynuclear complexes: synthesis, structure, and magnetic properties of copper(II) and nickel(II) complexes with a 2-aminoglucose ligand
    Burkhardt, Anja
    Spielberg, Eike T.
    Simon, Sascha
    Görls, Helmar
    Buchholz, Axel
    Plass, Winfried
    Chemistry - A European Journal, 2009, 15 (05): : 1261 - 1271
  • [38] SYNTHESIS OF NOVEL DINICKEL(II) AND NICKEL(II)-COPPER(II) BIMETALLIC COMPLEXES DERIVED FROM AN ACYCLIC DINUCLEATING SCHIFF BASE-PYRIDINE LIGAND
    LAM, F
    WANG, RJ
    MAK, TCW
    CHAN, KS
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (21) : 2439 - 2440
  • [39] Synthesis, reactivity and physico-chemical properties of novel chloro complex of nickel(II) containing benzoxazole ligand
    Dubey, Raj Kumar
    Mishra, Chandrakant M.
    Baranwal, Pragya
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2008, 85 (04) : 387 - 394
  • [40] New dinuclear nickel(II) and iron(II) complexes with a macrocyclic ligand containing a N6S2 donor-set: Synthesis, structural, MALDI-TOF-MS, magnetic and spectroscopic studies
    Nunez, Cristina
    Bastida, Rufina
    Macias, Alejandro
    Valencia, Laura
    Ribas, Joan
    Luis Capelo, Jose
    Lodeiro, Carlos
    DALTON TRANSACTIONS, 2010, 39 (33) : 7673 - 7683
12345