Verification of X-ray absorption parameters of some cobalt (II) and copper (II) complexes with randic indices

被引：0

作者：

Mishra, A ^{[1
]}

Dave, M ^{[1
]}

Khadikar, PV ^{[1
]}

Joshi, A ^{[1
]}

机构：

[1] Devi Ahilya Univ, Sch Phys, Indore 452017, India

来源：

INDIAN JOURNAL OF PURE & APPLIED PHYSICS | 2000年 / 38卷 / 04期

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D O I：

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中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

The application of Randic indices (chi) for verification of X-ray absorption near edge structure parameters of some Co(II)-complexes and Cu (II) complexes with a series of hydroxamic acid ligands is described. Chemical shifts (Delta E) and fractional oxidation numbers (Z(eff)) have been correlated with these indices. The regression analysis of indices have indicated that the chemical shift and fractional oxidation number are sensitive to the topological structure of coordinating ligands. These can be successfully used for estimating and investigating these parameters.

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页码：263 / 268

页数：6

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