Synthesis, Crystal Structure and Spectra Properties of the Nickel (II) Complex with 1,3-bis(1-benzylbenzimidazol2-yl)-2-Oxopropane

被引:16
|
作者
Wu, Huilu [1 ]
Yun, Ruirui [1 ]
Li, Ke [1 ]
Wang, Kaitong [1 ]
Huang, Xingcai [1 ]
Sun, Tao [1 ]
机构
[1] Lanzhou Jiaotong Univ, Sch Chem & Biol Engn, Lanzhou 730070, Peoples R China
关键词
crystal structure; nickel complex; spectra properties; ANTIPROTOZOAL; DERIVATIVES; BINDING;
D O I
10.1080/15533170903328735
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A novel complex of nickel (II) picrate with V-shaped ligand 1,3-bis(1-benzylbenzimidazol-2-yl)-2-oxopropane (Bobb) was synthesized and characterized by elemental analyses and electrical conductivity, IR and UV/visible spectra. The crystal structure of the complex has been determined by the single-crystal X-ray diffraction. In the complex, the Ni (II) ion is six-coordinated with a N4O2 ligand set, resulting in a distorted octahedron.
引用
收藏
页码:614 / 617
页数:4
相关论文
共 50 条
  • [21] Synthesis and crystal structure characterization of iron(II), cobalt(II) and nickel(II) complexes with 1,3-bis(2-pyridylmethylthio)propane
    Patra, Animesh
    Sarkar, Sandipan
    Drew, Michael G. B.
    Zangrando, Ennio
    Chattopadhyay, Pabitra
    POLYHEDRON, 2009, 28 (07) : 1261 - 1264
  • [22] 1,3-Bis(2-alkyltetrazol-5-yl)triazenes and their Fe(II), Co(II) and Ni(II) complexes: Synthesis, spectroscopy, and thermal properties. Crystal structure of Fe(II) and Co(II) 1,3-bis(2-methyltetrazol-5-yl)triazenide complexes
    Serebryanskaya, Tatiyana V.
    Ivashkevich, Ludmila S.
    Lyakhov, Alexander S.
    Gaponik, Pavel N.
    Ivashkevich, Oleg A.
    POLYHEDRON, 2010, 29 (14) : 2844 - 2850
  • [23] Crystal structure of 1,3-bis(2,3-dimethylquinoxalin-6-yl)benzene
    Diesendruck, Charles E.
    Rubin, Gabrielle
    Bertke, Jeffery A.
    Gray, Danielle L.
    Moore, Jeffrey S.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : 1429 - +
  • [24] Synthesis, Crystal Structure and Fluorescent Property of a Zn(Ⅱ) Complex with 1,3-Bis(imidazol-1-yl)benzene and 1,3-Benzenedicarboxylate
    张春丽
    郑和根
    结构化学, 2016, 35 (07) : 1070 - 1076
  • [25] The crystal structure of 1,3-bis(2,4-dinitro-1H-imidazol-1-yl)propane
    Chen, Cong
    Liu, Lulu
    Zhang, Jihui
    He, Jinfeng
    Chen, Lizhen
    Wang, Jianlong
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2024, 239 (05): : 949 - 950
  • [26] A V-shaped ligand 1,3-bis(1-methylbenzimidazol-2-yl)-2-oxapropane and its Cu(II) complex: Synthesis, crystal structure, antioxidation and DNA-binding properties
    Wu, Huilu
    Kou, Fan
    Jia, Fei
    Liu, Bin
    Yuan, Jingkun
    Bai, Ying
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY B-BIOLOGY, 2011, 105 (03) : 190 - 197
  • [27] Synthesis and complexation behaviour of 1,3-Bis(2-pyridylimino)isoindole with nickel(II)
    Sener, M. Kasim
    ASIAN JOURNAL OF CHEMISTRY, 2007, 19 (03) : 1870 - 1874
  • [28] An efficient synthesis of 1,3-bis(1,4,7-triazacyclonon-1-yl)-2-hydroxypropane, [1,3-bis(TACN)-2-propanol]
    Florio, P.
    Campi, E. M.
    Potdar, M. K.
    Jackson, W. R.
    Hearn, M. T. W.
    GREEN CHEMISTRY LETTERS AND REVIEWS, 2012, 5 (03) : 251 - 254
  • [29] 1,3-bis(silyl)cyclodisilazane: synthesis and crystal structure
    Jaschke, B
    Herbst-Irmer, R
    Klingebiel, U
    Neugebauer, P
    Pape, T
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (18): : 2953 - 2954
  • [30] Synthesis, Crystal Structure and Luminescent Properties of 2D Zinc Coordination Polymers Based on Bis(1,2,4-triazol-1-yl)methane and 1,3-Bis(1,2,4-triazol-1-yl)propane
    Semitut, Evgeny
    Sukhikh, Taisiya
    Filatov, Evgeny
    Ryadun, Alexey
    Potapov, Andrei
    CRYSTALS, 2017, 7 (12):