Application of La0.3Sr0.7Fe0.7Ti0.3O3-δ/GDC electrolyte in LT-SOFC

被引:21
|
作者
Zhou, Xiaomi [1 ]
Zhou, Fen [1 ]
机构
[1] Inner Mongolia Univ Sci & Technol, Sch Mat & Met, Baotou 014010, Peoples R China
基金
中国国家自然科学基金;
关键词
Low temperature solid oxide fuel cell; La0.3Sr0.7Fe0.7Ti0.3O3-delta/GDC-DC composite; Ionic-semiconductor electrolyte;
D O I
10.1016/j.ijhydene.2020.01.171
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Recently semiconductor-ionic electrolytes have capture much attentions for its promising application in low temperature solid oxide fuel cells. In this paper, semiconductor La0.3Sr0.7Fe0.7Ti0.3O3-delta (LSTF) and ionic Ce0.9Gd0.1O2-delta (GDC) composites are investigated. The new composite consisting of LSTF and GDC are used as ionic-semiconductor electrolytes for LT-SOFC. It was found that when the ratio of LSTF to GDC was 5:5, the performance of the fuel cell is the best. The open circuit voltage is 0.92 V, and the power density is 654 mW cm(-2) at 600 degrees C. Its electrical performance is much higher than that of traditional SOFC at low temperature. The energy band of different semiconductor is discussed by using optical equipment. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:9988 / 9995
页数:8
相关论文
共 50 条
  • [1] Effects of electrospraying parameters on deposition of La0.3Sr0.7Fe0.7Cr0.3O3-δ cathode layer on GDC
    Akkurt, Sedat
    Sindirac, Can
    Egesoy, Tugce Ozmen
    Atici, Gokce
    Erisman, Elif
    Ergen, Emre
    Buyukaksoy, Aligul
    [J]. INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY, 2023, 20 (03) : 1512 - 1525
  • [2] Synthesis and characterization of La0.7Sr0.3Fe0.7Co0.3O3±δ by Sonochemistry
    Elena, de La Huerta-Hernandez G.
    Ivan, Castro Cisneros
    Jose, A. Chavez Carvayar
    Isaias, Hernandez Perez
    [J]. MRS ADVANCES, 2020, 5 (61) : 3163 - 3170
  • [3] Synthesis and characterization of La0.7Sr0.3Fe0.7Co0.3O3±δ by Sonochemistry
    De La Huerta Hernández G. Elena
    Castro Cisneros Iván
    Carvayar José A. Chávez
    Hernández Pérez Isaías
    [J]. MRS Advances, 2020, 5 : 3163 - 3170
  • [4] Structural and electrochemical properties of Pr0.3Sr0.7Co0.3Fe0.7O3-δ cathode for IT-SOFC
    Park, Kwangjin
    Lee, Changbo
    Bae, Joongmyeon
    Yoo, Youngsung
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (16) : 6852 - 6860
  • [5] Electrochemistry of La0.3Sr0.7Fe0.7Cr0.3O3-δ as an oxygen and fuel electrode for RSOFCs
    Molero-Sanchez, Beatriz
    Addo, Paul
    Buyukaksoy, Aligul
    Paulson, Scott
    Birss, Viola
    [J]. FARADAY DISCUSSIONS, 2015, 182 : 159 - 175
  • [6] Nitrous oxide decomposition over La0.3Sr0.7Co0.7fe0.3O3-δ catalyst
    Hartley, U. W.
    Tongnan, V
    Laosiripojana, N.
    Kim-Lohsoontorn, P.
    Li, K.
    [J]. REACTION KINETICS MECHANISMS AND CATALYSIS, 2018, 125 (01) : 85 - 97
  • [7] Nitrous oxide decomposition over La0.3Sr0.7Co0.7Fe0.3O3−δ catalyst
    U. W. Hartley
    V. Tongnan
    N. Laosiripojana
    P. Kim-Lohsoontorn
    K. Li
    [J]. Reaction Kinetics, Mechanisms and Catalysis, 2018, 125 : 85 - 97
  • [8] Oxygen Permeation Properties of La0.7Sr0.3Co0.3Fe0.7O3-delta Membrane
    Son, Sou Hwan
    Kim, Jong-Pyo
    Park, Jung Hoon
    Lee, Yongtaek
    [J]. KOREAN CHEMICAL ENGINEERING RESEARCH, 2009, 47 (03): : 310 - 315
  • [9] CO/CO2 Study of High Performance La0.3Sr0.7Fe0.7Cr0.3O3- Reversible SOFC Electrodes
    Addo, P. K.
    Molero-Sanchez, B.
    Chen, M.
    Paulson, S.
    Birss, V.
    [J]. FUEL CELLS, 2015, 15 (05) : 689 - 696
  • [10] La0.3Sr0.7Ti0.3Fe0.7O3-δ derived from Malaysian ilmenite and monazite for application of solid oxide fuel cell cathode
    Ahmad, Muhammad Zaid
    Ahmad, Sahrim Haji
    Chen, Ruey Shan
    Ismail, Aznan Fazli
    Somalu, Mahendra Rao
    Hazan, Roshasnorlyza
    [J]. International Journal of Hydrogen Energy, 2024, 94 : 1247 - 1256