SOLID-STATE PROPERTIES OF MESOMORPHIC COPOLYMERS CONTAINING OXADIAZOLE AND FLUORENE UNITS

被引：27

作者：

Damaceanu, Mariana-Dana ^{[1
]}

Marin, Luminita ^{[1
]}

Manicke, Thomas ^{[2
]}

Bruma, Maria ^{[1
]}

机构：

[1] Petru Poni Inst Macromol Chem, Iasi 700487, Romania

[2] Univ Potsdam, Inst Phys & Astron, Potsdam, Germany

来源：

SOFT MATERIALS | 2009年 / 7卷 / 03期

关键词：

Mesophase; Photoluminescence; Polyoxadiazoles; SILICON; FILMS; POLY(1,3,4-OXADIAZOLE-AMIDE)S; POLYAZOMETHINES; OLIGOMERS; BEHAVIOR;

D O I：

10.1080/15394450903163748

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A series of copolymers containing oxadiazole and fluorene cromophores was synthesized by polycondensation of a diacid chloride incorporating one diphenylsilane linkage and a mixture of aromatic diamines containing oxadiazole and fluorene moieties. The solubility, thermal behavior, and photoluminescence ability of the thin polymer films were studied and compared with related heterocyclic polymers. These polymers are semicrystalline and form plastic mesophases in the first heating run, which brings about new ordered melted state processing opportunities. They exhibited blue photoluminescence in nanometric films, thus being promising candidates for manufacturing electroluminescent devices.

引用

页码：164 / 184

页数：21

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