Synthesis and polymerization of 3,3′-dialkyl-2,2′-bithiophenes

被引：39
|
作者：
Hoffmann, KJ
Bakken, E
Samuelsen, EJ
Carlsen, PHJ [1 ]
机构：
[1] Norwegian Univ Sci & Technol, Dept Chem, Trondheim, Norway
[2] Norwegian Univ Sci & Technol, Dept Phys, N-7491 Trondheim, Norway
来源：
SYNTHETIC METALS | 2000年 / 113卷 / 1-2期
关键词：
conjugated polymers; heterocycle synthesis; polythiophene and derivatives;
D O I：
10.1016/S0379-6779(00)00183-1
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A series of 3,3'-dialkyl-2,2'-bithiophenes (DAT2s) has been synthesized by the nickel-catalyzed Kumada coupling of 2-bromo-3-alkylthiophene with 2-(3-alkylthienyl) magnesium bromide. These monomers were analyzed by NMR and UV-Vis spectroscopies. The monomers were oxidatively polymerized with iron(III) chloride to yield the respective pi-conjugated poly(3,3'-dialkyl-2,2'-bithiophene)s. The new polymers were characterized with H-1 NMR and UV-Vis spectroscopies. Conductivity was in the order of 10-10(2) S/cm, depending upon the length of the alkyl chain. (C) 2000 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：39 / 44
页数：6
相关论文
共 50 条
  • [41] A NEW SIMPLE SYNTHESIS OF 3,3'-DIAMINO-2,2'-BIPYRROLES
    GLASER, M
    GRUNER, M
    VIOLA, H
    JOURNAL FUR PRAKTISCHE CHEMIE-CHEMIKER-ZEITUNG, 1994, 336 (04): : 363 - 365
  • [42] Synthesis of a chiral 3,3′-di-tertbutyl-2,2′-bipyrrole
    Skowronek, P
    Lightner, DA
    MONATSHEFTE FUR CHEMIE, 2003, 134 (06): : 889 - 899
  • [43] SYNTHESIS OF 2,2-DIALKYL-3-HALOPROPANENITRILES FROM 2,2-DIALKYLETHANENITRILES AND DIHALOMETHANES
    CLIFFE, IA
    TODD, RS
    WHITE, AC
    SYNTHETIC COMMUNICATIONS, 1990, 20 (12) : 1757 - 1767
  • [44] The synthesis and mesomorphic properties of 4,4"-dialkyl-2,2′,3-and 2,2′,3′-trifluoro-1,1′:4′,1"-terphenyls for high dielectric biaxiality ferroelectric liquid crystal mixtures
    Glendenning, ME
    Goodby, JW
    Hird, M
    Toyne, KJ
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 2000, (01): : 27 - 34
  • [45] SYNTHESIS AND PROPERTIES OF 2,2'-BIPYRIDIN-3-OLS AND 2,2'-BIPYRIDIN-3,3'-DIOLS
    SIEMANOWSKI, W
    WITZEL, H
    LIEBIGS ANNALEN DER CHEMIE, 1984, (10): : 1731 - 1739
  • [46] 3,3-DIALKYL 3-GERMA THIETANES - SYNTHESIS AND REACTIVITY
    BARRAU, J
    RIMA, G
    SATGE, J
    SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1984, 14 (01): : 21 - 37
  • [47] Facile synthesis of 3,3-dialkyl-6-phenylimidazopyridinones
    Jiang, Weiqin
    Fiordeliso, James J.
    Sui, Zhihua
    SYNTHETIC COMMUNICATIONS, 2007, 37 (7-9) : 1237 - 1249
  • [48] Synthesis and characterization of bis(3,4-ethylene-dioxythiophene)-(4,4′-dialkyl-2,2′-bithiazole) co-oligomers for electronic applications
    Cao, J
    Kampf, JW
    Curtis, MD
    CHEMISTRY OF MATERIALS, 2003, 15 (02) : 404 - 411
  • [49] An easy and efficient method for the synthesis of 2,2-dialkyl-3-nitrochromene
    Yan, MC
    Jang, YJ
    Yao, CF
    TETRAHEDRON LETTERS, 2001, 42 (14) : 2717 - 2721
  • [50] 3,3'-DISUBSTITUTED 2,2'-BIPHENOLS - SYNTHESIS OF NONPLANAR, TETRADENTATE CHELATING LIGANDS
    SORRELL, TN
    ELLIS, DJ
    JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (26): : 5765 - 5769
12345