Cumene hydroperoxide decomposition in the presence of organic zinc salts

被引：3
|
作者：
Nurullina, N. M. [1 ]
Batyrshin, N. N. [1 ]
Kharlampidi, Kh. E. [1 ]
机构：
[1] Kazan State Technol Univ, Kazan, Russia
来源：
PETROLEUM CHEMISTRY | 2006年 / 46卷 / 05期
关键词：
D O I：
10.1134/S0965544106050082
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Cumene hydroperoxide degradation in chlorobenzene in the presence of zinc naphthenate was studied. It was found and kinetically corroborated that the degradation is preceded by the formation of an intermediate complex of the hydroperoxide with the catalyst monomeric form. The kinetic and thermodynamic parameters of the complex are close to those recently found for zinc 2-ethylhexanoate. A procedure for the calculation of the concentration of the catalyst monomeric form from kinetic data is proposed.
引用
收藏
页码：349 / 352
页数：4
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