Preparation of atomically dispersed Cu species on a TiO2 (110) surface premodified with an organic compound

被引：21

作者：

Chun, Wang-Jae

Koike, Yuichiro

Ijima, Kaoru

Fujikawa, Keisuke

Ashima, Hidenori

Nomura, Masaharu

Iwasawa, Yasuhiro

Asakura, Kiyotaka ^{[1
]}

机构：

[1] Hokkaido Univ, Catalysis Res Ctr, Sapporo, Hokkaido 0010021, Japan

[2] Hokkaido Univ, Dept Quantum Sci & Engn, Sapporo, Hokkaido 0608628, Japan

[3] Univ Yamanashi, Dept Elect Engn, Kofu, Yamanashi 4008510, Japan

[4] Inst Mat Struct Sci, Photon Factory, Tsukuba, Ibaraki 3050801, Japan

[5] Univ Tokyo, Grad Sch Sci, Dept Chem, Tokyo 1130081, Japan

来源：

CHEMICAL PHYSICS LETTERS | 2007年 / 433卷 / 4-6期

基金：

日本学术振兴会; 日本科学技术振兴机构;

关键词：

D O I：

10.1016/j.cplett.2006.11.080

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Highly dispersed monoatomic Cu species on a TiO2 (110) surface were successfully prepared by a new method in which the TiO2 (110) surface was premodified with a 3-thiophenecarboxylic layer. Polarization-dependent total reflection fluorescence-X-ray absorption fine structure (PTRF-XAFS) showed the three dimensional structure of the monoatomic Cu species which were stabilized on the surface through the formation of Cu-S (adsorbate) and Cu-O (bridging oxygen) bonds. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：345 / 349

页数：5

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