Synthesis and characteristics of Zanthoxylum bungeanum seed oil-based alkyd resin modified by epoxy resin and their blends with HMMM

被引：17
|
作者：
Ma, Yangmin [1 ]
Lei, Rui [1 ]
Jiang, Yajuan [1 ]
机构：
[1] Shaanxi Univ Sci & Technol, Coll Chem & Chem Engn, Shaanxi Key Lab Chem Addit Ind, 7 Xuefu Rd, Xian 710021, Shaanxi, Peoples R China
来源：
POLYMER BULLETIN | 2020年 / 77卷 / 09期
关键词：
Waterborne coating; Alkyd resin; Epoxy resin; Zanthoxylum bungeanum seed oil; PERFORMANCE; ACID; NANOCOMPOSITE; OPTIMIZATION; PET;
D O I：
10.1007/s00289-019-02980-z
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Waterborne alkyd resins based on Zanthoxylum bungeanum seed oil modified with epoxy resin were prepared by polyesterification reaction. The different base catalysts were examined on the alcoholysis reaction. Further, epoxy-modified waterborne alkyd resins were blended with hexamethoxy methyl melamine to improve the properties like curing time, chemical resistance and thermal stability. The properties of the prepared resins (acid value, drying time, pencil hardness, adhesion, flexibility, chemical resistance and thermal stability) were studied. The prepared polymers were characterized by FT-IR spectroscopy, particle size analysis and thermogravimetric analysis. ZSO-based alkyd resins modified epoxy resin and their blends with HMMM (EWA:HMMM = 3:1) showed enhanced chemical resistance, physical properties and thermal stability. [GRAPHICS] .
引用
收藏
页码：4697 / 4711
页数：15
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