Fabrication and characteristics of rutile TiO2 nanoparticles induced by laser ablation

被引:37
|
作者
Liu Pei-sheng [1 ,2 ,3 ,4 ]
Cai Wei-ping [2 ]
Wan Li-xi [3 ]
Shi Ming-da [4 ]
Luo Xiang-dong [1 ]
Jing Wei-ping [1 ]
机构
[1] Nantong Univ, Jiangsu Key Lab ASCI Design, Nantong 226019, Peoples R China
[2] Chinese Acad Sci, Inst Solid State Phys, Key Lab Mat Phys, Anhui Key Lab Nanomat & Nanotechnol, Hefei 230031, Peoples R China
[3] Chinese Acad Sci, Inst Microelect, Beijing 100029, Peoples R China
[4] Nantong Fujitsu Microelect Co Ltd, Nantong 226006, Peoples R China
基金
中国国家自然科学基金;
关键词
TiO2; rutile; laser ablation; nanoparticles; photoluminescence; FILMS;
D O I
10.1016/S1003-6326(10)60143-4
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
The laser ablation technique was employed to prepare TiO2 nanoparticles by pulsed laser ablation of a titanium target immersed in the poly-(vinylpyrrolidone) solution using wavelength of 1 064 rim. The as-prepared products were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). The results indicate that the rutile TiO2 nanoparticles are synthesized at room temperature and the average size is about 35 nm with narrow size distribution. A possible formation mechanism was discussed and the UV-vis absorption and photoluminescence were measured. The optical study shows that rutile nanoparticle possesses direct optical transition with band gap of 3.15 eV.
引用
收藏
页码:S743 / S747
页数:5
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